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You have not given any details about the Operating system you are using and the monitor models you will be using along with the hardware configuration. Anyways, here are the general steps:

1. Click Start, and then click Control Panel.
2. Click Appearance and Themes, and then click Display.
3. On the Settings tab, click Identify to display a large number on each of your monitors. This shows which monitor corresponds with each icon.
4. Click the monitor icons and drag them to positions that represent how you want to move items from one monitor to another, and then click OK or Apply to view changes.
An excellent guide to setup dual monitor is given here at http://www.microsoft.com/athome/organization/twomonitors.aspx please go through this and interpret it as per the setup you have.

Here’s to Good Karma